Thanks, Brendan. From various posts I can now read the hidden message and get the relationship with the extra letter words. But I still don't understand what the 'thematic modification' is (although it will presumably explain why I can't make sense of the first letter of 21d, for example). I've now got 11a (thanks). I can make a guess at 3d from the crossers (two possible words) but can't parse it. This is driving me crazy. Maybe my complete unfamiliarity with the entity referenced by the theme is the problem.
Ilippu,
In 22 the extra letter comes from a 3 letter word for rent.
In 24 the extra letter is from a 2 letter abbreviation for infrared.
Does that help?
For 3d I can find a word that fits, an anagram of one of the words plus a single letter from another. But it seems unrelated to the clue. I can think of a way of changing the first letter of what I presume is the definition, but that doesn't relate to my answer.