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Pretty sure Jono is right about 5d

The anagram works if the solution to 32a is pharmaceutical.

@Damstraat22

I think there is only one possible answer for 42a if the puzzle's title is a hint, but for 45a there seem to be three options so like you I have gone for the 'Navajo' one as it's the most familiar.

I agree with Jono et al re 5d

For some weird reason stuck on 41d 'It borders this little land and former ferry point across the Severn.' Hints please

Gourami,
Think of “It” as a two letter code. I note the abbreviated “little land” is in Collins but not Chambers.
Some UK-specific GK required for the rest.

I had two answers that were consistent with the title - one a small town in the borough of Bexley and a hyphenated one of non-English origin.
I've gone with the former.

Ah, yes. I've just discovered your hyphenated one. My apologies for querying you earlier

@geting

No problem.