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6d - I want rope and act to get orchestration (12 two words)
I have Toast Master - why I now don't know but a correct answer would be much appreciated

a quick bit of googling for me when I did this one and ... dada.... TOWER CAPTAIN

I would never have got that in a million years but conversely will never forget it either - many thanks xwordfan

A "tower captain" is the leader of a group of bellringers!

22a. Plant that's yellow to a degree (5) -RPI-.
33a. Kind to show embarrassment, needing to show hint of red (5) -E-RE.
15d. Put in new design, new art form with inner energy (8) RE---MA-.
25d. Group of civilians in ancient city (5) ILI--.

15 reformat (anagram : art form + e)

25 Ilian (hidden in clue)

33 genre (kind) ?

22 Orpin?