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28 D; Machine with two or more functions.
5 Letters: C****

30 A: Most comfortable and unpretentious
9 Letters: H***I*E*T

31A: An international children's charity
7 & 8: *A*L*A* / C***G*E*

Combi

Homeliest

Railway Children

http://en.wikipedia.org/wiki/Railway_Children_%28charity%29

18d Imperilled

Mamya:
I had thought Railway Children would fit but never knew it was a charity. I've learned something.

Thanks
Cresson

You're welcome