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Can anyone help me with these short lues please ?

1. Best opportunity (3,4,6) ??? - ??i? - c???c?

2. Rubbish (5,6) ?a?t? - ????e?

3. Endure adversity (4,4,5) ???? - ?n?s - ???t?

4. Heavy spectacle frames (4-4) ???? - r?m?

5. Russian prince (11) ?e?????????

1 the main chance
4 horn rims?

4 dark-rims?

3 grit ones teeth

thanks for the 3 answers ,the answer for rubbish is waste matter.

i have more letters for clue 5
5. Russian prince (11) ?e?a?e?????

CESAREVITCH?

There are variant spellings - see http://dictionary.reference.com/browse/cesarevitch

thanks to everyone who helped with the answers.

can anyone help me with this last clue please ?

* Laid over touching (4) U???

UPON

thank you chrise for the answer .