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4d, I???t?, Beginners leaving rig on site set on fire.
9a, P?o?o??, Part of speech supporting no multinational organisation.
14a, E?r?h?, They are mostly awfully coarse.
23d, ?g?g, Excited to to have a game in East Germany , initially.

rig on site without 1st letters = ig n ite.
pro no UN.

anagram of They ar[e] = earthy
looks like Agog - not sure why tho.

Thanks, trevor

agog.
a = a
go = a japanese board game ( a game in East).
g = G[ermany)

Thanks ,Trevor, I think 9a, is Pronoun.