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Stuck with a few
32a holiness 5 ltrs. ?i?s?
41d ironical 9 ltrs. ?d?e???a?
46a Gayeaux. 5 ltrs c?a??
38d feature of the face 4 ktrs. ????
all above, connecting words/clues.

21a be acceptable 4,6 ltrs. P?s? M?s?e?
54d manly, masculine 6 ltrs. R?r?l?
I think maybe made a few mistakes in this c/word.

21 pass muster

32 piety ?

54 virile ?

46. gateaux . cakes

41 does skeptical fit ?

38d lips
41d satirical

Thanks Jazzgirl & scorpiojo, everything fits apart from, 41a. Ironical 9 ltrs
?d?i?i?a?
the d comes from the answer to 29d
French breakfast pastry, 4,2,8
pain ,du, chocolat ?? Maybe wrong with this.

Pain au chocolat

pain au chocolat