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Holier than thou mama has nothing on this painter (7)

PI

CASS Elliot of the Mamas & Papas

O

painter in charge of donkey in Italian river (7)

In charge of donkey = IC ASS

Italian river = PO

tweak to @14

Artwork revealed by Olympic Association? (7)

Created a good impression early on? (7) or (5,7)

Artist exhibiting pic as soon as possible (7)

Forerunner of the CIA paints a pic (7)

OSS a pic

Overheard choice of rope to behead painter (7)

Theatre designer for film on Garland is uninitiated (7)

Pic (l)asso
Garland - rope/lasso

Picasso was a theatre designer - creator of sets and scenery for theatrical productions. Can be applied to film and TV.

Painter framed by philanthropic associate (7)

Hundred and one gains for west Texas town losing the Spanish painter (7)

CI (el) PASSO