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Mulled ale knowledge contained in pepper pot (5)

One of these a day keeps The Doctor away? Possibly (5)

Killer from Skaro is held back by Bike Lady(5)

Lead and potassium compound found to be lethal by many doctors (6)

Curly kale and, lastly, something to finish off (5)

VOTING NOW OPEN

I liked pigale @5, dorrien @23 and BBM2 @24, but my pick is

mattrom @16
(However did you find it, mattrom?)

Some in-depth knowledge on display including mattrom's pest (cyberman). As nemo acknowledged, a difficult answer to come up with a "something out of the ordinary" definition (cryptic or otherwise) with smooth wordplay and the implausible chemistry aside (I believe there's an alloy rather than compound, chrise?) I have BBM2 @ 24 runner up to aristo @ 13; love the definition.

@ginge: aristo@13? Do you mean spike@13 or aristo@17?

Like: mattrom@2, ginge@4

Vote: paul@7