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51d alchera

69 starosta

Thanks SG

http://www.collinsdictionary.com/dictionary/english/starosta
OS inside start + a

thanks Chris

33d Some mediaeval lords reviewed one learned in Ireland (5)

o?l?v

Ollav , reversed in clue

http://www.merriam-webster.com/dictionary/ollav

33d Some mediaeval lords reviewed one learned in Ireland (5)
O?l?v
80d Refuge marshal had set up (10) ???r?s?a?a
100d German car carries our new S. African housewife (5)
S?o?w
82a Another vacuous ape hint: everything is in a state of flux. Everything is in a state of flux. (5,4)
86d Lighthouse chamber left map out. Weigh anchor? (4,4)

33 Ollav a learned man in ancient Ireland

Thanks Mamya. I couldn't see it for looking at it.