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I've finished talking to myself now. Will go and get lunch. ;)

Dick = A private investigator?

crossed in the post. Thanks mamya

stuck on last two intersecting clues:

41ac Rare element in a drug, ecstasy (8)
???a?i?e

36dn Work with such simple arrangement, less hard for Christian singing (6,5)
g???e?m?s?c
help please!

gospel music?

astatine?

gospel music:

go +suc(h) simple (anagram)

a statin (drug) e(cstasy)

many thanks for the parsing of the answers to jazz and chris!

I've noticed I do not have all the parsing for 10d
answer: halitosis(offensive condition)

clue: a drunk so upset, restricted by his offensive condition

a drunk: a sot (reversed)
(restricted by) his
This leaves IL not accounted for.