I'll try...
Go to
http://www.quinapalus.com/playfair.html
Click on playfair breaker
Hopefully you have 3 crossing letters for 36a with 2nd one blank I?CO
hopefully you have the clue answer to 36a ... WINE so wine >>>I?CO
Type in wine in the "plain text" box and in the box underneath "to ciphertext", type in IACO (going to try all the possibles for that 2nd letter...) Press search ....gives you the keyword nightcap (which might be the keyword we are looking for or it might not...)
Now go right through the alphabet using B,C,D....Z.......not as tedious as it sounds..........there are only 3 letters that actually work.
Hopefully you will recognise which of the 3 is your keyword.
Once you have the keyword you will be able to put your other clue answers in code and the 4 unclued are "part of the keyword" when deciphered.
Come back again if you get stuck...