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A word for refined & heraldic tincture with a inside

Hi barny
That's one of the ones I haven't parsed. My definition is "second pen" (as in writer)

Thanks zozozo - I didn't get near that meaning of "refined".

Is 13d an anagram of tutee not and r?
Tutee not excited about nucleus of charged or, possibly, uncharged particle (9)

Yes

The two remaining ones I don't understand (and may have got wrong!) are:

9a It could go off with a bang in Hollywood this evening (6)
I have "this evening" as it might be written in Hollywood. I don't see why, except three of its letters might be explosive.

7 Commonly used in Frankfurter dips? (2,3,4)
Why "Frankfurter"? I haven't been able to find a relevant German translation of the last word.

..and surely this clue is wrong
10a Allowed bill to add up, so this wine sent back (8)
The reversal indicator isn't in the right place

Frankfurt river

Thanks zozozo

Thanks zozozo - never heard of that one either!

Chrise at 16. The whole word is a form of explosive.