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Caution Djokovic, primarily for what he did after hitting the net (8)

Caution - reserve
Djokovic, primarily - D

Kept mostly in aspic, perhaps? (8)

(P)RESERVED

Private soldiers did their duty (8)

private=def
soldiers=RE (Royal Engineers)
did their duty=served

K.G.I.C on radio remote? (8)

On radio - sounds like (cagey, icy - both "reserved") definition - remote.

Sorry bobs mum, missed the bit about explanations too as I did it on the phone this morning and can't read the small print too good.

Post 2)
Withdrawn benefit that's owing? (8)

Withdrawn = Def
benefit = serve
owing = 'in the red'

Sorry from me too, Bob's Mum, I didn't read the preamble.
My post #4 is just a double definition.

Like cold fish thrown up on plate? (8)

Double definition.
(Forgive me- but have you ever been to a sushi bar?)

Dammed, not damned, cheeky! (8)

Double definition.

Initially Roy Emerson delivered the ball and kept cool. (8)

Kept cool = defn.
R(oy) E(merson) =RE (old tennis

She did another spell on the Witches Council and so quiet and shy (8)
Did another.....Re - served
Quiet and shy = DEF