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1 Across, Rock band's first album (50% off )roughly around number one
(7) ??????A

5 Across, Joyce's central character, oddly calm after being taken in by police reveals antagonist of Ulysses (7) NO LETTERS

9 Across, 24 carat gold is melted down with tin (9) ??????T??

11 Across, Height of fashionable elegance? Monarch prompted hippy diet (8) ??????E?

Many thanks

5 cyclops

(Jo)y(ce) c(a)l(m) inside cops

9a authentic (24 carat)

11a chic k pea

1 breccia (rock)
b- band's first
album rec (ord) 50%off
roughly - ca
one - i

Many thanks to you all.

I cannot parse authentic apart from au - gold, but the answer seems to fit

jazzgirl - The clue should read "THE tin".

Ah! thanks David