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Stuck with a few
100a lesser than 5 ltrs. ?e?o?
112a neat appearance ( I put tidiness) 8 ltrs
????n?s?
102d release from bonds 5 ltrs
?n?d? (My d comes from tidiness)

100 below

112a Primness?
102d Untie?

or Trimness

Chrisg and mattrom, still having difficulty with above clues
lets start again.
95a with a hard shiny surface, 8 ltrs
?e?a!l?? (I put metallic)
97d flower-patterened cotton fabric 6 ltrs
??i?t? (I put chintz) C from metallic. T from, 112a neat appearance Tidiness, primness would p in 97d, can't find answer to that then
hope you can understand above, sorry to be a pest, hate when can't get crossword finished

Would mattrom's suggestion of trimness not work?

Ooooops sorry, did'nt notic Mattroms answer, of trimness, apologies and thanks, to mattrom, chrisg and yourself zozozo for help.