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I give in ! Nearly there , but I just can't get my last 3.
52a) Journalist serving American holds forth bottles for stars(3,6) I have R?D ???N?S
46a) One's thick skinned, heading off chaos and trouble(7) I have A?O???O. (Avocado???)
45d) Documents of old photographer found by younger one(6) I have ???Y??.

Any help would be very much appreciated!

45 Papyri, old documents.,
46 Avocado, thick skinned. (H)avoc and Ado.

52 red giants 46 yes 45 papyri.

Avocado looks right - ( h)avoc + do

Thank you very much Malone. That all makes good sense!

Glad I could help. I had 'Red Giants' but wasn't sure of the parsing, so left that one!

Thanks zozozo