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All answers have 'un' in part of the answer
5)red wine (8)
10)Reject or forsake(8)
12)daze, astonish(4)
24)Perimeter border (8)
36)Sheffield and manchester together (6)
39)Mixture of several ingredients (8)
42)A commemorative plaque (10,5)
44) A bed cover (11)

36 United

thanks chrisg

12 Stun

Hello Bigfoot - 12 Stun 24 Boundary

5 Brunello

10 Renounce

39 Compound

44) counterpane

Thanks so much