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22a. Joseph, say, in Cuba with flower child (6) c?i???
23. Reach unity on democratic policy (8) ?i?????e

chippy - slang for carpenter?

Thanks Tevor,
Makes sense - that gives a letter for 17d. Form of carbon found in layer in fruit ?r?p?e?e which I thought originally was graphite but can't be due to the e third last. Grapheme is all I can think of but it's not a form of carbon

graphene - hen in grape?

Thanks again - knew it was grape round something but I wasn't familiar with graphene