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Really stuck with these five:-
5a. Be united with business in this place (6) c - - - r -
9a. Bosses accepting I love university, being diligent
(8) e - u - - - u -
11a. Bragged about the sailors (4) - - e -
22a. When speaking, becomes more tense, seeing giants. (6) - I - a - s
6d. Trim musical score. (7) - - - - - - t

Any help greatly appreciated.

Hair - musical - cut - score = haircut- trim?

5 Cohere

Titans (giants) sounds like tightens?

Crew?

9 Studious

Studs + I O U

Are you sure of the e? - studs- bosses with I , o - love and u - university - studious - diligent?

The e comes from 4d. Tall canoeists crashed into settlements (13) c - - - e - l - t - o - s. I put in cancellations and the third letter is that 'e'

Thank you about and mamma for your help

I meant ab and mamya