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11d The point at which one shoulders duties? (3,9)

I have ?a? / T?R?S?O?D
If the answer is Pay threshold - why?

26a Limitlessly level, note (4)
I have E?E?

23d Sin sounding not viciousinitially (4)
I have ?N? Y
If the answer is Envy - why?

N V = Not Viscious, the first letters, NV.

TAX THRESHOLD (tax = duty)

(L)EVE(L) + N = level

Many thanks all