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I've tied myself in a knot in the middle of this one. Help with one might sort me out (hopefully)
33d Not out to stop a nation producing radioactive material.
I have A?????n?
I think I may have other letters but these are quite likely to be totally misleading.

astatine in=home inside a state

Many thanks, imagcq. Never heard of it but hopefully it will help me sort out the rest.

Now all that's left is 14a Broad area of disagreement with monarch and people.
I have n?r?o?a.
Any but the A could be wrong.
Thanks in advance.

norfolk?

no+r+folk

Thanks Andyc - now wonder I was struggling when the only letter I thought was right was the one that was wrong!. Feel daft now!

We've all done that Mary, don't beat yourself up.