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Last 2 clues-interdependent.* where they share a common letter.
16d)Miles from camp to uni, cracking place for a puncture(8)
(A)--*-I-T
20ac)Peacekeepers report with energy and drive from head office in Rome, maybe.(6)
U-*-P-
(Could 20ac. be UNPOPE? But why?)

UN (peacekeepers) + pop (report) + e (energy)?

acupoint?

UN=peacekeepers
pop=repore=energunpope=drive from office

Oh yes...seems obvious once you've explained it. Thanks. That makes the other one
(A)--P-I-T

Thanks, Tony and AB. Well misdirection certainly worked well against me there. I kept thinking of cars, and AUTO plus etcs..,