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Stuck with last 4 clues.
46a (7) letters. Distressed. ??R???D.
45d.(4) letters. Audible breath. ???H.
96d (6) letters. Fatal Viral Disease. ???EES.
100a (6) letters. Functional. U????E.
They are probably straightforward, but after weekend brain for in proper use yet.

Hi Jinty, are you sure of your letters? If not, 100a could be USEFUL

45d Sigh

45 d is probably sigh

maybe some letters are wrong ?
as fatal viral disease could be rabies or herpes ?

Sorry so late in getting back with my thanks, to Wendy, NellyB, Guardian, & Andelia. Alls well now, had made a few mistakes.

46 will be worried