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20)First stage of Alpine glaciation begins in German, Uganda and New Zealand (4)
17)Beyond Gateshead, delicate ornamental fabric is iced with sugar (5)
33)Cathedral on the diameter, perhaps (2,5)
3)Straightforward shot (5-5)
59)Firn is not even in the right order (4)
76)Lauder' parting drrink (5-2-6)
80)Adhesive tape for a master key (5-7)
100)Intended to begin friendship in a nice chat every evening (7)

20 Gunz - first glacial stage

17 Glace

100 Fiancee

Thanks so much chrisg

3. point blank

bigfoot - what is the first word of 59? Fern?

59 does say FIRN, thanks for trying

76 Deoch an dorius? ( Scottish for drink at the door)

59 Just Google - firn